1. Product Overview of CAS 13601-19-9 Sodium ferrocyanide anhydrous
Sodium Ferrocyanide (Anhydrous), also known as Tetrasodium Hexacyanoferrate(II), Yellow Prussiate of Soda (anhydrous grade). It is a stable inorganic coordination complex. Compared with decahydrate sodium ferrocyanide (CAS:14434-22-1), anhydrous type contains no crystal water, lower moisture content, superior anti-caking performance and stable storage property. The cyanide group is tightly coordinated with iron ions; free cyanide is not easily released under normal temperature and neutral environment. Widely applied as food anti-caking additive, pigment raw material, metallurgical and electroplating auxiliary chemical.
2. Basic Chemical Information
Product Name: Sodium Ferrocyanide (Anhydrous)
Aliases: Tetrasodium Hexacyanoferrate(II), Yellow Prussiate of Soda
CAS No.: 13601-19-9
EINECS No.: 237-081-9
Molecular Formula: Na4Fe·(CN)6
Molecular Weight: 303.91
Appearance: Pale lemon-yellow crystalline powder or granular crystal
Odor: Odorless
Solubility: Soluble in water; practically insoluble in ethanol and organic solvents
Thermal Stability: Stable below 400℃; decomposes above 435℃
Aqueous solution: Weakly alkalineImportant Distinction
✅ CAS 13601-19-9 = Anhydrous Sodium Ferrocyanide (No crystal water)
✅ CAS 14434-22-1 = Sodium Ferrocyanide Decahydrate (Contains 10 crystal water)
3. Core Product Features
- Anhydrous formula, low free moisture, not easy to deliquesce or agglomerate during long-distance sea transportation
- Excellent anti-caking function for refined salt, sea salt and industrial granular materials
- High crystal purity, low heavy metal and insoluble impurities, consistent batch quality
- Raw material to synthesize Prussian blue pigment, sodium ferricyanide and other cyanide coordination salts
- Available in Food Grade (E535) and Industrial Grade for diversified market demands
4. Main Applications
- Food Industry (Food Grade E535)
Anti-caking agent for edible salt, sea salt, preventing salt crystal adhesion and caking during storage and transportation.
- Coating & Ink Industry
Key raw material for manufacturing iron blue (Prussian blue) pigments used in paints, printing inks and water-based coatings.
- Metallurgy & Heat Treatment
Auxiliary agent for steel surface carburizing treatment, metal surface cleaning & anti-tarnish treatment.
- Fine Chemical Industry
Starting material for producing sodium ferricyanide and other ferrocyanide series products.
- Other Fields
Photographic auxiliary chemical, mineral flotation reagent, wastewater heavy metal chelating agent.
5. Typical Specifications Food Grade / Industrial Anhydrous Grade
Assay (as Na4Fe·(CN)6): ≥99.0%
Moisture: ≤0.50%
Water Insoluble Matter: ≤0.01%
Chloride (Cl⁻): ≤0.02%
Sulfate (SO4): ≤0.02%
Heavy Metals (Pb): ≤10 ppm
Arsenic (As): ≤1 ppm
6. Packing & Storage
Packing: 25kg composite woven bag with PE inner liner; 1200kg jumbo FIBC bulk bag available.
Storage: Store in cool, dry, ventilated warehouse; keep hermetically sealed to avoid moisture absorption. Isolate from strong mineral acids and strong oxidants.
Shelf Life: 24 months under proper sealed storage.
7. Safety & Transportation
UN 3077, Class 9 Environmentally Hazardous Substance, Packing Group III.
Avoid dust inhalation and direct contact with skin and eyes.⚠️ Warning: When mixed with concentrated strong acid, toxic hydrogen cyanide gas will be generated.




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