Product name: Polyisobutylene (PIB)
CAS No.: 9003-27-4
Synonym: Poly(isobutene)
Linear Formula: (C4H8)x
Brief Introduction
Polyisobutylene (PIB) is a saturated aliphatic homopolymer manufactured via cationic polymerization of isobutylene monomer. Commercial grades cover low, medium and high molecular weight variants. Low-molecular-weight PIB appears as colourless to pale yellow viscous liquid; high-molecular-weight grades exist as elastic, rubbery semi-solid. It is basically odourless, non-toxic and chemically inert.
Thanks to its fully saturated hydrocarbon molecular backbone, PIB features outstanding resistance against oxidation, ozone, ultraviolet radiation, dilute acid and dilute alkali. It possesses extremely low gas permeability, good hydrophobicity, excellent electrical insulation and low-temperature flexibility. It does not contain unsaturated double bonds, so aging resistance is far superior to many general diene-based rubbers.
Typical Physical & Chemical Properties
Appearance: Colourless to light yellow viscous liquid or rubber-like semi-solid
Density (20 ℃): 0.91 ~ 0.93 g/cm³
Refractive Index (n₂₀ᴰ): 1.505 ~ 1.510
Flash Point (Open Cup): ≥240 ℃
Solubility: Soluble in aliphatic hydrocarbons, aromatic hydrocarbons, mineral oil and chlorinated solvents; insoluble in water, ethanol, methanol and other polar solvents
Glass Transition Temperature: approx. -65 ~ -75 ℃
Stability: Stable under ambient conditions; avoid long-term contact with strong oxidants and high temperature above 250 ℃
Quality Specifications (Standard Industrial Grade)
| Item | Specification | Test Method |
|---|---|---|
| Appearance | Colourless to pale yellow homogeneous material | Visual Inspection |
| Colour (Pt-Co) | ≤ 50 Hazen | Platinum-Cobalt Method |
| Water Content | ≤ 50 ppm | Karl Fischer Titration |
| Ash Content | ≤ 0.01 % | Gravimetry |
| Volatile Matter | ≤ 0.08 % | Gravimetry (105 ℃, 2 h) |
Note: Viscosity & molecular weight are customized indicators based on customer designated grade.
Main Applications
- Lubricant & fuel additive: viscosity modifier, dispersant for engine oil, gear oil and fuel formulations
- Adhesive & sealant raw material: hot-melt adhesives, butyl sealant blends, waterproof sealing compounds- Rubber & plastic modifier: improve air tightness, shock absorption and weather resistance of rubber products
- Cosmetic raw material: thickener, film-forming agent and emollient in skin care & hair care formulations
- Food-contact compliant chewing gum base material (food-grade PIB)
- Electrical industry: insulating compound for cables, wires and electronic encapsulation
- Asphalt modifier, anti-corrosion coating and anti-rust auxiliary for metal surface protection
Packing, Storage & Transportation
Packing: 200L coated steel drum; bulk IBC tank available. Keep packages sealed against impurities.
Storage: Store in cool, dry and ventilated warehouse at 5–35 °C. Keep away from direct sunlight, open flame and strong oxidants. Shelf life: 24 months.Transportation: Non-hazardous goods. Secure drums to avoid collision and leakage. Do not transport together with oxidants, corrosives and food materials. Prevent overheating under high temperature.



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