AIBN (2,2'-Azobis(2-methylpropionitrile), CAS 78-67-1) is an oil-soluble azo radical initiator supplied as white crystalline powder, offered in 98% and 99% assay grades for free radical polymerization of monomers and copolymers. TNJ Chemical is the key manufacturer and exporter since from 2001 in China. We guarantee high quality, competitive price, stable supply, fast delivery and tech support etc. To find more, please contact sales@tnjchem.com
Product Information
Chemical Name 2,2'-Azobis(2-methylpropionitrile)
Common Name AIBN, Azobisisobutyronitrile
CAS No. 78-67-1Molecular Formula C₈H₁₂N₄
Molecular Weight 164.21
EINECS No. 201-132-3UN Number UN 3234
IMDG Hazard Class 4.1 (Self-reactive substances)
Packing Group II
Chemphysical Properties
Appearance: White crystalline powder
Melting Point: 102–104 °C (with decomposition)
10-hour half-life temperature: 65 °CDensity: 1.11 g/cm³
Solubility: Insoluble in water; soluble in methanol, chloroform and other organic solvents
Odor: Odorless
Thermal hazard: Heat sensitive. It will decompose and release gas when heated, avoid high temperature and impact
Recommended storage temperature: 2–8 °C, maximum storage temperature ≤20℃
Quality Specification
| Item | Specification |
|---|---|
| Appearance | White crystalline powder |
| Assay (HPLC) | ≥98.0% / ≥99.0% |
| Loss on Drying | ≤0.50% |
| Melting Range | 102 ~ 104℃ (decomposition) |
| Residue on Ignition | ≤0.10% |
| Heavy Metal (Pb) | ≤10 ppm |
Use & Application
AIBN is a classic oil-soluble free radical initiator for polymerization and copolymerization. It is commonly used in production of polystyrene, polyacrylic resin, polyacrylonitrile, PVC and synthetic rubber. Nitrogen gas is generated during its thermal decomposition, so it can also be applied as foaming agent for plastics and rubber. It is also used in academic lab for free radical reaction research. Its decomposition products are toxic, so it cannot be used for food-contact or medical packaging polymer materials.
Packing
20kg per carton with inner PE plastic bag. Customized packing is available upon request.
Delivery & Storage
Keep container tightly sealed. Store in cool, dry and well ventilated warehouse. Keep away from direct sunlight, heat sources and high temperature. Store separately from oxidants, acids, alkalis and combustible materials. Transport as IMDG Class 4.1 UN3234 self-reactive solid. Avoid heavy collision and high temperature exposure during transportation.



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