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Acesulfame-K, Acesulfame Potassium, AK sugar CAS 55589-62-3 is a calorie-free sugar substitute (artificial sweetener), also known as Acesulfame K or Ace K (K being the symbol forpotassium). Acesulfame K is 200 times sweeter than sucrose (table sugar), it is a highly stable, crystalline sweetener with a chemical structure is similar to saccharin.